”イオン液体”と”メタンハイドレート”
和歌山工業高等専門学校 生物応用化学科
綱島研究室
Tsunashima Lab.
Department of Applied Chemistry and Biochemistry,
National Institute of Technology, Wakayama College
国際会議発表(2009~) Presentaion at international conferences
(46) K. Hori, S. Nawate, M. Matsumoto, Y. Tsuchida, K. Tsunashima, H. Yamada, "Dependence of Cation Structures on Electrochemical
Polymerization of Aniline in Phosphonium Ionic Liquids", 2024 Pacific Rim Meeting on Electrochemical and Solid-State Science,
Oct 7, 2024, Honolulu, Hawaii, USA.
(45) K. Kawabata, S. Azuma, J. Shimada, Y. Tsuchida, K. Tsunashima, T. Sugahara, A. Tani, "Introduction of Cyclic Structures into
Phosphonium Salts As Potential Guest Substances for Ionic Semiclathrate Hydrates", 2024 Pacific Rim Meeting on
Electrochemical and Solid-State Science, Oct 7, 2024, Honolulu, Hawaii, USA.
(44) S. Kikuchi, K. Nishikawa, T. Kawaji, K. Tsunashima, H. Hotta, A. Yokobiki, Y. Tsuchida, Y. Funasako, H. Yamada, "Physicochemical
and Thermal Behaviors of Room-Temperature Phosphonium Ionic Liquids Based on Fluorosulfonyl(trifluoromethylsulfonyl)amide
Anion as Potential Electrolytes", 2024 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 7, 2024, Honolulu,
Hawaii, USA.
(43) H. Akamatsu, S. Kubo, S. Kikuchi, K. Hotta, A. Yokobiki, Y. Tsuchida, K. Tsunashima, Y. Funasako, Y. Okuno, H. Yamada, A. Tani,
"Dependence of Carboxylate Anions on Physicochemical Properties of Tributyloctylphosphonium-Based Ionic Liquids",
2024 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 7, 2024, Honolulu, Hawaii, USA.
(42) K. Hori, S. Nawate, M. Matsumoto, Y. Tsuchida, K. Tsunashima, H. Yamada, "Design of Phosphonium Ionic Liquids for
Electrochemical Polymerization of Aniline", 10th International Symposium on Molecular Thermodynamics and Molecular
Simulation, Aug 28, 2024, Koriyama, Fukushima.
(41) K. Kawabata, S. Azuma, J. Shimada, Y. Tsuchida, K. Tsunashima, T. Sugahara, A. Tani, "Phase Equilibrium Behavior of
Semiclathrate Hydrates Based on Quaternary Phosphonium Bromides Containing Alicyclic Structures", 10th International
Symposium on Molecular Thermodynamics and Molecular Simulation, Aug 28, 2024, Koriyama, Fukushima.
(40) H. Akamatsu, S. Hasegawa, S. Kikuchi, Y. Tsuchida, K. Tsunashima, H. Hotta, A. Yokobiki, Y. Funasako, Y. Okuno, H. Yamada,
A. Tani, "Preparation and Physicochemical Characterization of Room-Temperature Ionic Liquids Based on Tributyloctyl-
phosphonium Cation and Alkanesulfonate Anions", 10th International Symposium on Molecular Thermodynamics and
Molecular Simulation, Aug 28, 2024, Koriyama, Fukushima.
(39) H. Akamatsu, K. Tsunashima, Y. Tsuchida, Y. Okuno, H. Yamada,, "Preparation and Physicochemical Characterization of
Phosphonium-Based Ionic Liquids Containing Carboxylate Anions", 2023 Joint Symposium on Molten Salts, Nov 14,
2023, Kyoto.
(38) K. Tsunashima, S. Kikuchi, K. Nishikawa, Y. Tsuchida, T. Kawaji, Y. Funasako, H. Yamada, "Comparative Study on Transport
Property of Asymmetric Fluorosulfonyl(trifluoromethyl-sulfonyl)amide-Based Phosphonium Ionic Liquids",
244th The Electrochemical Society Fall Meeting, Oct 11, 2023, Gothenburg, Sweden.
(37) H. Akamatsu, K. Tsunashima, Y. Tsuchida, Y. Okuno, H. Yamada, "Preparation and Physicochemical Characterization of
Phosphonium-Based Ionic Liquids Containing Carboxylate Anions", 243rd The Electrochemical Society Spring Meeting,
May 31, 2023, Boston, MT, USA. (Digital)
(36) K. Tsunashima, S. Hasegawa, H. Akamatsu, Y. Tsuchida, Y. Okuno, H. Yamada, "Preparation and Physicochemical
Characterization of Hydrophilic Alkanesulfonate-Based Phosphonium Ionic Liquids", The 1st KOSEN Research International
Symposium (KRIS2023), Mar 1, 2023, Tokyo.
(35) H. Akamatsu, K. Tsunashima, Y. Tsuchida, Y. Okuno, H. Yamada, "Phosphonium Ionic Liquids Based on Carboxylate Anions
As Potential Electrolyte Materials", The 1st KOSEN Research International Symposium (KRIS2023), Mar 1, 2023, Tokyo.
(34) S. Azuma, K. Tsunashima, J. Shimada, T. Sugahara, A. Tani, "Phosphonium Salts As Potential Guest Substances for Ionic
Semiclathrate Hydrates", 242nd The Electrochemical Society Fall Meeting, Oct 12, 2022, Atlanta, GA, USA. (Digital)
(33) K. Tsunashima, S. Hasegawa, Y. Okuno, H. Yamada, "Physicochemical Characterization of Sulfonate-Based Phosphonium
Ionic Liquids", 242nd The Electrochemical Society Fall Meeting, Oct 11, 2022, Atlanta, GA, USA. (Digital)
(32) K. Tsunashima, N. Yasugi, J. Shimada, T. Higashi, Y. Sakaguchi, H. Yamada, A. Tani, "Characterization of Polythiophene
derivatives electrochemically doped in phosphonium ionic liquids", The 14th International Symposium on Organic Reactions,
Apr 25, 2020, Yokohama.
(31) D. Nomizu, K. Tsunashima, Y. Sakaguchi, T. Higashi, H. Yamada, M. Matsumiya, "Ionic Conductivity and Thermal Stability
of Polyethylene Glycol Based Polymer Electrolytes Containing Phosphonium Ionic Liquids", 236th The Electrochemical
Society Fall Meeting, Oct 15, 2019, Atlanta, GA, USA.
(30) N. Yasugi, K. Tsunashima, T. Higashi, Y. Sakaguchi, H. Yamada, M. Matsumiya, "Electrochemical Behavior of Selenophene
in Quaternary Ammonium and Phosphonium Based Ionic Liquids", 236th The Electrochemical Society Fall Meeting,
Oct 14, 2019, Atlanta, GA, USA.
(29) D. Nomizu, Y. Tsuchida, K. Tsunashima, H. Yamada, M. Matsumiya, "Improvement of Conductivity of Polymer Electrolytes
Based on Phosphonium Ionic Liquids", 6th Asian-Pacific Congress on Ionic Liquids & Green Processes, Nov 1, 2018,
Yonago, Tottori.
(28) J. Shimada, T. Sugahara, H. Yamada, K. Tsunashima, "Ionic Conductivities in Ionic Clathrate Hydrates Based on Quaternary
Ammonium and Phosphonium Salts", 6th Asian-Pacific Congress on Ionic Liquids & Green Processes, Nov 1, 2018,
Yonago, Tottori.
(27) K. Tsunashima, N. Yasugi, K. Nishihata, M. Matsumiya, "Electrochemical Behavior of Polythiophene Derivatives in
Phosphonium Ionic Liquids", 6th Asian-Pacific Congress on Ionic Liquids & Green Processes, Nov 1, 2018, Yonago, Tottori.
(26) M. Shimada, T. Sugahara, K. Tsunashima, "Thermodynamic Stabilities of Tetra-n-butylphosphonium + Gas Semiclathrate
Hydrate Systems", 8th International Symposium on Molecular Thermodynamics and Molecular Simulation, Sep 7, 2018,
Narashino, Chiba.
(25) J. Shimada, M. Shimada, T. Sugahara, K. Tsunashima, "Phase Equilibrium Relations of Semiclathrate Hydrates Based on
Tetra-n-butylphosphonium Formate, Acetate, Propionate and Lactate", 8th International Symposium on Molecular
Thermodynamics and Molecular Simulation, Sep 7, 2018, Narashino, Chiba.
(24) K. Tsunashima, Y. Tsuchida, D. Nomizu, H. Yamada, M. Matsumiya, "Effect of phosphonium ionic liquids on thermal stability
of polymethyl methacrylate polymers", 8th International Symposium on Molecular Thermodynamics and Molecular Simulation,
Sep 7, 2018, Narashino, Chiba.
(23) M. Shimada, J. Shimada, K. Tsunashima, C. Aoyama, "Methodology to Collect Natural Gas from Methane Hydrate Deposits
Using Sunlight: Design of Direct Sunlight Exposure System", 2017 American Geophysical Union Fall Meeting, Dec 11, 2017,
New Orleans, LA, USA.
(22) J. Shimada, M. Shimada, K. Tsunashima, C. Aoyama, "Utilization of Sunlight into Methane Hydrate Production: Feasibility Study
Based on Energy Balance Estimation", 2017 American Geophysical Union Fall Meeting, Dec 11, 2017, New Orleans, LA, USA.
(21) J. Shimada, K. Tsunashima, M. Ue, K. Iwasaki, T. Tsuda, S. Kuwabata, N. Hirai, H. Kanematsu, T. Kogo, A. Ogawa,
"Physical and Electrochemical Properties of Ionic Liquids Based on Quaternary Phosphonium Cations and Carboxylate Anions
as Electrolytes", 2016 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 4, 2016, Honolulu, Hawaii, USA.
(20) K. Nishihata, K. Tsunashima, Y. Ono, M. Matsumiya, "Electropolymerization of Thiophenes in a Bis(fluorosulfonyl)amide Based
Phosphonium Ionic Liquid", 2016 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 4, 2016,
Honolulu, Hawaii, USA.
(19) K. Tsunashima, N. Minami, Y. Ono, M. Imoto, S. Mori, M. Takeda, "Electrochemical Behavior of Aromatic Diamines and the Growth
of Conducting Films", 2016 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 5, 2016, Honolulu, Hawaii, USA.
(18) K. Tsunashima, K. Nishihata, K. Honma, D. Ito, Y. Ono, M. Matsumiya, "Design of phosphonium ionic liquids for electrosynthesis
of conducting polymers", Aug 24, 2016, The Hague, Netherlands.
(17) K. Nishihata, K. Tsunashima, M. Matsumiya, Y. Ono, "Tetracyanoborate Anion Based Phosphonium Ionic Liquids as Electrolytes
for Pyrrole Electropolymerization", 229th The Electrochemical Society Spring Meeting, May 31, 2016, San Diego, CA, USA.
(16) K. Nishihata, K. Tsunashima, M. Matsumiya, "Preparation and physicochemical properties of phosphonium ionic liquids based on
tetracyanoborate anion", 66th Annual Meeting of the International Society of Electrochemistry, Oct 5, 2015, Taipei, Taiwan.
(15) K. Tsunashima, H. Fujimoto, H. H. Wang, L. Curtiss, K. Amine, Y. Mizuguchi, "Electrochemical behavior of oxygen in phosphonium
ionic liquids as lithium-air battery electrolytes", 66th Annual Meeting of the International Society of Electrochemistry, Oct 9, 2015,
Taipei, Taiwan.
(14) K. Tsunashima, Y. Sakai, M. Matsumiya, "Physical and Electrochemical Properties of Room-Temperature Ionic Liquids Containing
Allyl-Based Phosphonium Cations and Bis(fluorosulfonyl)amide Anion", May 26, 2015, Chicago, IL, USA.
(13) K. Tsunashima, S. Kikuchi, C. Nagai, Y. Sakai, M. Matsumiya, "Influence of Aromatic and Unsaturated Substituents on Physical
and Electrochemical Properties of Phosphonium Ionic Liquids", 224th The Electrochemical Society Fall Meeting, Oct 29, 2013,
San Francisco, CA, USA.
(12) K. Tsunashima, T. Matsubayashi, Y. Ono, M. Matsumiya, "Electrosynthesis of Polypyrrole in Low-Viscosity Ionic Liquids",
2012 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 10, 2012, Honolulu, Hawaii, USA.
(11) K. Tsunashima, H. Taguchi, F. Yonekawa, "Influence of Nonflammable Diluents on Properties of Phosphonium Ionic Liquids as
Lithium Battery Electrolytes", 2012 Pacific Rim Meeting on Electrochemical and Solid-State Science, Oct 9, 2012,
Honolulu, Hawaii, USA.
(10) K. Tsunashima, T. Matsubayashi, Y. Ono, "Electropolymerization of pyrrole in 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)amide
ionic liquid", 63rd Annual Meeting of the International Society of Electrochemistry, Aug 21, 2012, Prague, Czech Republic.
(9) K. Tsunashima, K. Kudo, "Electrochemical behavior of quaternary phosphonium ionic liquids based on benzotriazolate anion",
63rd Annual Meeting of the International Society of Electrochemistry, Aug 20, 2012, Prague, Czech Republic.
(8) K. Tsunashima, S. Kikuchi, Y. Yamanaka, M. Matsumiya, Y. Ono, "Physical and electrochemical properties of ionic liquids based
on p-bond-containing phosphonium cations", 63rd Annual Meeting of the International Society of Electrochemistry, Aug 20, 2012,
Prague, Czech Republic.
(7) K. Tsunashima, H. Taguchi, A. Kawabata, F. Yonekawa, S. Kodama, "Properties of phosphonium ionic liquid-based electrolytes for
lithium secondary batteries", 63rd Annual Meeting of the International Society of Electrochemistry, Aug 20, 2012,
Prague, Czech Republic.
(6) K. Tsunashima, A. Kawabata, H. Taguchi, F. Yonekawa, S. Kodama, "Highly Conductive and Nonflammable Ionic Liquid Electrolytes
Containing Phosphazene Compounds for Lithium Secondary Batteries", 220th The Electrochemical Society Fall Meeting, Oct 10, 2011,
Boston, MA, USA.
(5) K. Tsunashima, S. Yamamoto, Y. Kunugi, S. Kodama, "Physical and electrochemical characterization of room-temperature
phosphonium ionic liquids based on cyano-containing anions", Sep 12, 2011, Niigata, Japan.
(4) K. Tsunashima, A. Kawabata, M. Matsumiya, S. Kodama, "Physical and electrochemical properties of bis(fluorosulfonyl)amide-based
phosphonium ionic liquids", 62nd Annual Meeting of the International Society of Electrochemistry, Sep 13, 2011, Niigata, Japan.
(3) K. Tsunashima, A. Kawabata, M. Matsumiya, S. Kodama, Y. Kunugi, "New Class of Bis(fluorosulfonyl)amide Ionic Liquids Based on
Quaternary Phosphonium Cations", 4th International Congress on Ionic Liquids, Jun 17, 2011, Arlington, Virginia, USA.
(2) K. Tsunashima, M. Sugiya, Y. Kunugi, "New class of room-temperature phosphonium ionic liquids based on a dicyanamide anion",
2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010), Dec 16, 2010, Honolulu, Hawaii, USA.
(1) K. Tsunashima, S. Kodama, M. Sugiya, Y. Ono, "Effect of Substituents on Physical and Electrochemical Properties of Phosphonium
Ionic Liquids as Lithium Battery Electrolytes", 4th International Conference on Polymer Batteries and Fuel Cells, Aug 3, 2009,
Yokohama, Japan.