”イオン液体”と”メタンハイドレート”
和歌山工業高等専門学校 生物応用化学科
綱島研究室
Tsunashima Lab.
Department of Applied Chemistry and Biochemistry,
National Institute of Technology, Wakayama College
国際会議プロシーディングス(2009~) Proceedings paper
(22) H. Akamatsu, S. Kubo, S. Kikuchi, Y. Tsuchida, K. Tsunashima,* H. Hotta, A. Yokobiki, Y. Funasako, Y. Okuno, A. Hamada,
H. Yamada, A. Tani*, "Dependence of Carboxylate Anions on Physicochemical Properties of Tributyloctylphosphonium-Based
Ionic Liquids", ECS Transactions, 114, (6), 89-95 (2024).
(21) S. Kikuchi, K. Nishikawa, T. Kawaji,* K. Tsunashima,* H. Hotta, A. Yokobiki, Y. Tsuchida, Y. Funasako, H. Yamada,
"Physicochemical and Thermal Behaviors of Room-Temperature Phosphonium Ionic Liquids Based on Fluorosulfonyl(trifluoro-
methylsulfonyl)Amide Anion As Potential Electrolytes", ECS Transactions, 114, (6), 81-88 (2024).
(20) K. Kawabata, S. Azuma, J. Shimada, Y. Tsuchida, K. Tsunashima,* T. Sugahara,* A. Tani, "Introduction of Cyclic Structures into
Phosphonium Salts As Potential Guest Substances for Ionic Clathrate Hydrates", ECS Transactions, 114, (6), 75-79 (2024).
(19) K. Tsunashima,* S. Hasegawa, Y. Okuno, H. Yamada, "Physicochemical Characterization of Sulfonate-Based Phosphonium
Ionic Liquids", ECS Transactions, 109, (14), 23-27 (2022).
(18) J. Shimada, M. Yamada, T. Sugahara,* A. Tani, K. Tsunashima, T. Hirai, "Thermodynamic properties of
tetra-n-butylphosphonium dicarboxylate semiclathrate hydrates ", Proceedings of 9th International Symposium on
Molecular Thermodynamics and Molecular Simulation, PA03 (2021).
(17) Y. Tsuchida, D. Nomizu, K. Tsunashima*, H. Yamada, M. Matsumiya, "Effect of Phosphonium Ionic Liquids on Thermal
Stability of Polymethyl Methacrylate Polymers", Proceedings of 8th International Symposium on Molecular Thermodynamics
and Molecular Simulation, pp36 (2018).
(16) Y. Tsuchida, M. Matsumiya,* K. Tsunashima, "Solvation structure and thermodynamics for lanthanide complexes in
ionic liquids evaluated by ADF and MD simulations", Proceedings of 8th International Symposium on Molecular
Thermodynamics and Molecular Simulation, pp34 (2018).
(15) T. Makino,* K. Tsunashima, M. Kanakubo,* "CO2 Absorption and Physical Properties of Tributyloctylphosphonium
Benzotriazolate", Proceedings of 8th International Symposium on Molecular Thermodynamics and Molecular Simulation,
pp32 (2018).
(14) M. Shimada, J. Shimada, T. Sugahara, K. Tsunashima,* "Thermodynamic Stabilities of Tetra-n-butylphosphonium + Gas
Semiclathrate Hydrate Systems", Proceedings of 8th International Symposium on Molecular Thermodynamics and
Molecular Simulation, pp13 (2018).
(13) J. Shimada, M. Shimada, T. Sugahara, K. Tsunashima,* "Phase Equilibrium Relations of Semiclathrate Hydrates Based on
Tetra-n-butylphosphonium Formate, Acetate, Propionate and Lactate", Proceedings of 8th International Symposium on
Molecular Thermodynamics and Molecular Simulation, pp11 (2018).
(12) H. Kanematsu,* A. Oizumi, T. Sato, T. Kamijo, S. honma, D.M. Barry, N. Hirai, A. Ogawa, T. Kogo, D. Kuroda, K. Tsunashima,
"Polymer Brush Made By Ionic Liquids and the Inhibition Effects for Biofilm Formation",
ECS Transactions, 85, (13), 1089-1095 (2018).
(11) H. Kanematsu,* T. Saito, D.M. Barry, N. Hirai, T. Kogo, A. Ogawa, K. Tsunashima, "Effects of Ionic Liquids on Biofilm Formation
in a Loop-Type Laboratory Biofilm Reactor", ECS Transactions, 80, (10), 1147-1155 (2017).
(10) J. Shimada, K. Tsunashima,* M. Ue, K. Iwasaki, T. Tsuda, S. Kuwabata, H. Kanematsu, N. Hirai, T. Kogo, A. Ogawa,
"Physical and Electrochemical Properties of Ionic Liquids Based on Quaternary Phosphonium Cations and Carboxylate Anions
As Electrolytes", ECS Transactions, 75, (52), 105-111 (2017).
(9) K. Nishihata, K. Tsunashima,* Y. Ono, M. Matsumiya, "Electropolymerization of Thiophene in a Bis(fluorosulfonyl)amide Based
Phosphonium Ionic Liquid", ECS Transactions, 75, (52), 99-103 (2017).
(8) A. Nishimura, M. Matsumiya,* K. Tsunashima, "Ionic conduction mechanism analysis for neodymium complex in phosphonium
ionic liquids and potassium bis(trifluoromethyl-sulfonyl)amide melts", ECS Transactions, 75, (15), 275-285 (2016).
(7) K. Nishihata, K. Tsunashima,* M. Matsumiya, "Physicochemical and Electrochemical Properties of Room-Temperature Ionic
Liquids Based on Quaternary Phosphonium Cations and Tetracyanoborate Anion", ECS Transactions, 72, (33), 9-15 (2016).
(6) K. Tsunashima,* Y. Sakai, M. Matsumiya, "Physical and Electrochemical Properties of Room-Temperature Ionic Liquids Containing
Allyl-Based Phosphonium Cations and Bis(fluorosulfonyl)amide Anion", ECS Transactions, 66, (27), 33-39 (2015).
(5) K. Tsunashima,* C. Nagai, M. Matsumiya, "Influence of Introducing a Benzyl Group on Physical and Electrochemical Properties
of Bis(fluorosulfonyl)amide-Based Phosphonium Ionic Liquids", ECS Transactions, 58, (46), 91-97 (2014).
(4) T. Yamauchi,* T. Matsui, T. Nishiyama, K. Tsunashima, N. Tsubokawa, S. Harada, "Development of Micro Hydrogen Gas Sensor
Utilizing Polymerized Gel with Ionic Liquid as a Solvent", ECS Transactions, 50, (12), 231-236 (2013).
(3) N. Tsuda, M. Matsumiya,* K. Tsunashima, S. Kodama, "Electrochemical behavior and solvation analysis of rare earth complexes
in ionic liquids media investigated by SECM and Raman spectroscopy", ECS Transactions, 50, (11), 539-548 (2013).
(2) H. Kondo, M. Matsumiya,* K. Tsunashima, S. Kodama, "Investigation of oxidation state of the electrodeposited neodymium metal
related with the water contents of phosphonium ionic liquids", ECS Transactions, 50, (11), 529-538 (2013).
(1) K. Tsunashima,* H. Taguchi, F. Yonekawa, "Influence of Nonflammable Diluents on Properties of Phosphonium Ionic Liquids as
Lithium Battery Electrolytes", ECS Transactions, 50, (11), 419-424 (2013).